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|Section2= |Section3= |Section7= |Section8= }} Sulfur tetrafluoride is the chemical compound with the formula SF4. This species exists as a gas at standard conditions. It is a corrosive species that releases dangerous HF upon exposure to water or moisture. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds,〔C.-L. J. Wang, "Sulfur Tetrafluoride" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. .〕 some of which are important in the pharmaceutical and specialty chemical industries. ==Structure== Sulfur in SF4 is in the formal +4 oxidation state. Of sulfur's total of six valence electrons, two form a lone pair. The structure of SF4 can therefore be anticipated using the principles of VSEPR theory: it is a see-saw shape, with S at the center. One of the three equatorial positions is occupied by a nonbonding lone pair of electrons. Consequently, the molecule has two distinct types of F ligands, two axial and two equatorial. The relevant bond distances are = 164.3 pm and = 154.2 pm. It is typical for the axial ligands in hypervalent molecules to be bonded less strongly. In contrast to SF4, the related molecule SF6 has sulfur in the 6+ state, no valence electrons remain nonbonding on sulfur, hence the molecule adopts a highly symmetrical octahedral structure. Further contrasting with SF4, SF6 is extraordinarily inert chemically. The 19F NMR spectrum of SF4 reveals only one signal, which indicates that the axial and equatorial F atom positions rapidly interconvert via pseudorotation.〔Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「sulfur tetrafluoride」の詳細全文を読む スポンサード リンク
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